Product ID:UNOCAL 76 UNLEADED PLUS 87 GASOLINE,M/H GRADE,PROD#:00406.
MSDS Date:11/11/1992
FSC:9130
NIIN:01-208-4172
MSDS Number: BVHJL

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 800-424-9300(CHEMTREC)/800-356-3129

Info Phone: 213-977-7589

Cage: 23034

UNION OIL CO OF CA UNION 76 DIV- WESTERN RGION

7600 LOS ANGELES, CA 90017-1443 US

Telephone: 213-977-7589

Cage: 79003

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 85-100%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM/500STEL;9394

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1-15%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-21%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-4%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9394

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INGEST/INHAL:SLIGHTLY TOXIC.IRRIT OF
NOSE/THORAT/RESP TRACT,CNS DEPRESSION. IRRIT OF DIGESTIVE TRACT,
LUNG INFLAMMATION/DAMAGE IF ENTERS LUNGS. SKIN:MILD IRRIT.PROL/REP
REDNESS/BURNING/DYRING/CRACKING .EYE:IRRITANT;EXPOSURE TO HI CONCEN
MAYASSOC W/CARDIAC ARRHYTHMIAS.EPINEPHRINE/OTHER MAY INITIATE
CARDIA ARRHYTHMIAS.
Explanation of Carcinogenicity:CONTAINS BENZENE. UNLEADED GASOLINE &
GASOLINE ENGINE EXHAUST HAVE BEEN IDENTIFIED AS POSSIBLE
CARCINOGENS BY IARC.
Effects of Overexposure:INGEST:NAUSEA, VOMIT, BLURRED VISION, FLUSHING,
SIGNS OF NSC DEPRESSION, RESP FAILURE, CONVULSIONS, UNCONSC/DEATH.
INHAL:COUGHING, NAUSEA, SIGNS OF CNS DEPRESSION
(HEADACHE,DROWSINESS,DIZZINESS,LOSS O F COORDINATION, FATIGUE),
SHORTNESS OF BREATH.EYE:STINGING, TEARING, REDNESS,SWELLING.
Medical Cond Aggravated by Exposure:PRE-EXITING SKIN & LUNG (E.G.
ASTHMA-LIKE CONDITIONS) DISORDERS. PRE-EXISTING HEART DISORDERS MAY
BE MORE SUSCEPTIBLE TO IRREG HEARTBEATS (ARRHYTHMIAS).

First Aid:EYE:MOVE TO FRESH AIR.FLUSH W/WATER FOR @ LEAST 15MINS
OPENING EYELIDS.GET MED ATTN.SKIN:WIPE EXCESS OFF.WASH W/MILD SOAP
& WATER OR WATERLESS SKIN CLEANSER.IRRIT/REDNESS DEVLPS/PERS GET
MED ATTN.INHA L:MOVE TO FRESH AIR.IF SYMP PERSIST GETIMMED MED
ATTN.NOT BREATH GIVE ART RESP.DIFF BREATH GIVE OXY.GET IMMED MED
ATTN.INGEST:POTENTIAL ASPIRATION HAZ.GET EMERG MED
ATTN.DROWSY/UNSCON PLACE (SUPPLE)

Flash Point Method:TCC
Flash Point:-45F,-43C
Extinguishing Media:DRY CHEMICAL, CARBON DIXOIDE, HALON, FOAM OR WATER
SPRAY IS RECOMMENDED. WATER MAY BE INEFFECTIVE.(NOTE:HALON IS A
ODS).
Fire Fighting Procedures:WEAR APPROPRIATE PROT EQPMT INCLUDING RESP
PROT AS CONDITION WARRANT.WATERSPRAY USEFUL IN MIN/DISPERS VAP/COOL
EQPMT EXPO TO HEAT/FLAME.AVOID SPREADING BURN LIQ
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM.IGN BY
HEAT/SPARKS/ETC.VAP TRAVEL DISTANCES WHERE MAY IGN &
FLASHBACK/EXPLODE.VAP/AIR EXPLOSION HAZ INDOOR/OUTDOOR/SEWER.VAP
HEAVIER THAN AIR.

Spill Release Procedures:KEEP IGN SOURCES/HOT METAL SURFACES AWAY.STAY
UPWIND.ISOLATE AREA/STOP SPILL W/O RISK.WEAR APPROPRIATE PPE AS
CONDITIONS WARRANT.PREVENT FROM ENTERING SEWER/STORM DRAIN/ETC.IF
SO CALL NAT RESP CNTR 80 0-424-8802.DIKE/ABSORB INTO APPRO
ABSORBENT MATL.
Neutralizing Agent:NONE SPECIFIED BY MFG.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED.OPEN SLOWLY
TO RELIEVE PRESSURE.USE/STORE IN COOL,DRY,WELL VENTILATED AREAS
AWAY FROM HEAT/DIRECT SUNLIGHT/HOT METAL SUR/ETC
Other Precautions:BOND/GROUND ALL EQPMT WHEN TRANSFERRING FROM VESSELT
TO ANOTHER.STORE ONLY IN APPROVED CNTNR.PROTECT FROM PHYS
DAMAGE.USE EXPLOSION-PROOF EQPMT.DO NOT ENTER CONFINED SPACES W/O
PROPER ENTRY PROCEDURES (ASTM D4276).OUTDOOR/DETACH STORAGE PREF

Respiratory Protection:THE USE OF RESP PROTECTION IS ADVISED WHEN
CONCEN EXCEED ANY ESTABLISHED EXPOSURE LIMITS. DEPENDING ON
AIRBORNE CONCEN USE RESP OR GAS MASK W/APPROPRIATE CARTRIDGES &
CANNISTERS(NIOSH APPORVED IF AVAI LABLE) OR SUPPLIED AIR EQPMT.
Ventilation:REQUIRED.ADDTN VENTIL/EXHAUST SYS MAY BE REQUIRED IF
CURRENT VENTIL PRACTICES AREN'T ADEQU.EQPMT SHOULD EXPLOSION PROOF.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:SAFETY GLASSES.
Other Protective Equipment:IT IS SUGGESTED THAT SOURCE OF CLEAN WATER
BE AVAILABLE IN WORK AREA FOR FLUSHING EYE/SKIN.IMPERVIOUS CLOTHING
AS NEEDED
Work Hygienic Practices:WASH THOROUGHLY AFT HANDLING.USE GOOD PERSONAL
HYGIENE PTRACTICE.DO NOT WEAR CONTAMIN CLOTH/SHOE.
Supplemental Safety and Health
1STAID:ON LEFT SIDE,HEAD DOWN.IF CONSC/ALERT INDUCT VOMIT IF INGEST
>5OZ MATL W/SYRUP OF IPECAC UNDER MED ATTN.STORAGE:EMPTY CNTNR
RETAIN RESIDUE & ARE DANGEROUS.DO NOT PRES/CUT/WELD/BRAZE/ETC SUCH
CN TNR.EMPTY DRUMS SHOULD BE DRAINED/BUNGED/SHIPPED TO
SUPPLIER/DRUM RECONDITIONER.

HCC:F1
Boiling Pt:B.P. Text:85.0F,29.4C
Vapor Density:>1
Spec Gravity:0.74
Evaporation Rate & Reference:>1, N-BUTYL ACETATE=1.
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:CLEAR LIQUID, GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CONTACT W/STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES &
DICHROMATES MAY CAUSE FIRE OR EXPLOSION.
Stability Condition to Avoid:EXTREMELY FLAMM LIQ/VAP. VAP MAY CAUSE
FLASH FIRE. AVOID ALL POSSIBLE SOURCES OF IGNITION.
Hazardous Decomposition Products:COMBUST MAY YIELD SIGNIFICANT AMTS OF
CARBON MONOXIDE & SMALL AMTS OF OXIDES OF SULFUR &
NITROGEN,BENZENE,OTHER ORG CMPD

Waste Disposal Methods:NOTIFY AUTHORITIES OF SPILLS/RELEASES. DISPOSE
OF PRODUCT IN ACCORDANCE W/LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.